Use this snippet before your script or page does any other output (put it on the first lines of the page)
<-- code start -->
<?php
header("Expires: Mon, 26 Jul 1997 05:00:00 GMT"); // Date in the past
header("Last-Modified: " . gmdate("D, d M Y H:i:s") . " GMT"); // always modified
header("Cache-Control: no-cache, must-revalidate"); // HTTP/1.1
header("Pragma: no-cache"); // HTTP/1.0
?>
<-- code end -->
You could also configure your http or proxy server not to cache these particular pages or any PHP pages on your site