That code has issues, how about:
$result = mysql_query("select id, title, company, city, country, catg FROM jobs WHERE approve=0");
$info = array(1 => 'Available', 2 => 'Not Available');
while ($row = mysql_fetch_assoc($result)) {
print 'Title: ' . $row['title'];
print 'Job Status: ' . $info[$row['catg']];
}
So, if catg is 1 it will print Available, if it is 2 it will print Not Available. Also notice how we just need one query, and define the $info array just once.