Well... it's principally used with classes...
Read this : http://www.php.net/manual/en/ref.classobj.php
Also, there is something similar that exists... "=>". You can use it with arrays...
$my_arr = array("item_1" => "value 1", "item_2" => "value 2");
Would give :
$my_arr["item_1"] = "value 1";
$my_arr["item_2"] = "value 2";
Do you understand now ?
Hope it helped.