The first thing you need to do is create the mySQL table, I hope you're using a tool like phpMyAdmin to access your DB, because that makes it easier for you.
In any case, you're table would have 4 fields, ID, SiteName, Info, url.
Set ID to Auto Increment, that way you achieve ID to automatically be one number higher than the last ID that was stored 🙂
Then you need to code your form to submit to your db.
I suggest reading a couple of tutorials, but it really is simple.
Your code would look something like this, but it could be different:
$sql=mysql_query("INSERT INTO `table_name` ( `ID` , `SiteName` , `Info` , `Url`)
HTH