OOh, boy...bash, I presume? Or are we talking GUI/X Windows? For the shell....
Use 'whereis' to find files and programs:
$whereis php.ini
$whereis ed
For modifying your php.ini/httpd.conf, I'd find out what editors I had available. vi and emacs are die hard UNIX emphasize hard (for beginners); I hear that Linux usually has vim, which is a bit lighter; ed is very limited. you might look for ee, pico, nano.... if whereis doesn't help you find them, look in /bin, /sbin, /usr/sbin, /usr/bin, /usr/local/bin,
/usr/local/sbin, and so on.... if you can't call them by name from the commandline, check your $PATH environment variable.
I hear that Linux manpages are pretty lousy, but they should be there. Try 'man mount' for mounting the floppy drive, and there should be manpages for most installed binaries (like the editors I mentioned).
To restart apache, try:
$apachectl restart (or stop, or start, or configtest)
If that doesn't work, you can call the apache binary directly if you know where it is.
$/usr/local/apache/bin/httpd restart
If PHP is installed as an Apache module, then you don't/can't turn it off. If a 'whereis PHP' gets you an answer, it's probably installed as a binary; otherwise you'll see stuff related to it in the httpd.conf file if it's "mod_php".
You'll have to get other help for PostGre; I do MySQL and am terrible at it, sorry.....
Oh, to view stuff. Gotta have GUI for that, and that's not my alley either... if you can find netscape or opera and call them up, maybe they'll do startx (or xdm or whatever) themselves, but I'm not into that....
HTH,
SELF-EDIT: FWIW, I've got UNIXHELP installed at www.daleco.biz
(free stuff from some University somewhere). Won't help with X Windows/GUI, but it's got a lot of terminology and stuff about the shell(s), even some things about editors, I believe.