Do you have PHP setup for command line processing? If so you will need to add #!/usr/bin/php (or whatever the path to your php command line interpreter is) to the top of the script to be run, and chmod it to be executable by the user who's cron job will run the script. Then you use 'crontab -e' to open up the list of cron jobs and enter the appropriate information:
0 3 * * 1,3 /path/to/php/script/myscript.php
This would run at 3am on every Monday and Wednesday, look at the crontab man pages for the proper setup of this file.
If you don't have PHP setup for command line processing then you will need to have a text only browser, like lynx, that you can use to call the page. If this is how you have to do it then you just need to replace the above /path/to/... with the appropriate lynx command to open and view the php page.