Did you look at [man]session_id[/man] while you were there?
session_id -- Get and/or set the current session id
Looking at that and one or two other things I noticed in the list at the left, I wrote
<?php
//Simulates first page; starts a session, writes stuff.
session_start();
$_SESSION['foo']='bar';
session_write_close(); //Simulates end of first page
//Simulates second page; starts a _different_ session, writes stuff.
session_id(md5(session_id())); // Guarantees different sess_id from original.
session_start();
$_SESSION['bar']='foo';
?>
Creates two session files: one containing $_SESSION['foo']='bar', and one containing $_SESSION['bar']='foo'.
But I've never found any cause to change the session_id mid-session, however: If I want to log users I log users, if I want to log sessions I log sessions. By not confusing the to I can log both and see multiple users in a single session, or a single user over multiple sessions.