I concur with the hard coding -- not a good idea. If you are opposed to creating a file or database containing the data, at the very least create an include file that just contains the movie time arrays, and include them into your PHP page where appropriate.
Also, include the name of the movie as part of your array:
$movie_a = array("Just Married", "11:05am", "1:05pm", "3:05pm", "5:05pm", "7:05pm", "9:05pm", "11:05pm");
$movie_b = array("Spider-man", "12:05am", "2:05pm", "4:05pm", "6:05pm", "8:05pm", "10:05pm", "12:05pm");
// etc...
$movies = array($movie_a, $movie_b, $movie_c, $movie_d)
//To extract a value:
$chosen_movie = $movies[0][0]; // Just Married
$chosen_time = $movies[0][3]; // 3:05pm
The good thing about doing it this way is that if you decide to use a database or file, the data will easily be read in to your variables.