7.4's still in beta, but it's looking like Win32 native operation, table spaces, and Point in Time Replication. If anything slips, it's likely to be PITR.
Point in Time Replication would be a HUGE win for postgresql. It would allow you to have a database that could basically be recovered to a known state in an exact moment in time after a hardware failure or system level crash.
It also lays the ground work for transaction log based replication, which should be a very fast synchronous sing master / multi slave system.
No guarantees of course, but that's the big stuff still in the works.
The TODO list is here:
http://developer.postgresql.org/todo.php
Note that lots gets put on the TODO list that isn't being worked on. It's kind of a grab bag for hackers to look at and ask if anyone else is working on it and get advice before trying to implement it.
In the mean time, ERserver is due out around 7.4's final release date as well. This is a replication server written in Java and well tested. I believe it's the replication that afilias usesd to host the .info and .org domains.