Be careful you don't destroy everybody else's sessions at the same time! If you do something like that (a straight delete) on a shared host who keeps all their session data in the one place, everybody's session data is going to be destroyed.
They aren't going to like that 🙂. Whilst a good host will give each user their own session temporary directory, it may not always be the case. You may also destroy session data for your other scripts that aren't related too!
Your best option would be to store your session data in a database. Then, simply do a DELETE * FROM session_table; when required - boom, all your sessions are gone.
For information in storing session data in other places other than the default files, look up the PHP function session_set_save_handler().