Well I'm going to give another bit of reasoning (better than numeric experiments) before giving the answer; mainly 'cos I've already written it and I don't want it to go to waste.
It has to be admitted that a few numeric experiments do not a proof make, however. Who knows, the pattern could go wonky with n=7, or 9, or 10, or.... What would be nice is something a little more solid. A chain of reasoning that doesn't involve conducting numeric experiments might go something like this:
Consider the set of all natural numbers less than 10n. Put that another way, all n-digit decimal numerals where those less than 10(n-1) have been padded with leading zeros (oh, but you can do that, because it doesn't affect how many numerals do or don't have a '3' in them! If you don't like it you can just keep the shorter numerals around and say that, e.g, '57' does not have a '3' in the thousands position - which is true!). How many of these numerals contain a '3'?
Well, ten percent of them have a '3' in the units position. In other words, (1/10) of them.
Of the remaining ninety percent (i.e., those that don't have a '3' in the units position), ten percent have a '3' in the tens position. That is to say, ten percent of ninety percent, or (1/10)(9/10).
Of the remaining ninety percent of those, ten percent have a '3' in the hundreds position. That's (1/10)(9/10)(9/10) = (1/10)(9/10)2.
Etc...
...of the remaining ninety percent of those, ten percent have a '3' in the - um - (n-1)illions position, (i.e., the "first" or leftmost position). That's (1/10)(9/10)(n-1).
Now let's add those all together.
(1/10) + (1/10)(9/10) + (1/10)(9/10)^2 + ... + (1/10)(9/10)^([i]n[/i]-1)
= (1/10)(1 + (9/10) + (9/10)^2 + ... + (9/10)^([i]n[/i]-1))
Oh, this is just summing a geometric progression! Talk about in-your-sleep!
[i]n[/i]-1
= (1/10)(SUM (9/10)^[i]i[/i])
[i]i[/i]=0
=(1/10)(1-(9/10)^[i]n[/i])/(1-9/10)
And simplify that a bit. (It really could do with a bit of simplification!)
=(1/10)(1-(9/10)^[i]n[/i])/(1-9/10)
=(1/10)(1-(9/10)^[i]n[/i])/(10/10-9/10)
=(1/10)(1-(9/10)^[i]n[/i])/(1/10)
=1-(9/10)^[i]n[/i]
Hurrraaaay.
If you want to be rigorous about that argument, it can be formulated in terms of induction on n.