preg_match("/TD class=s align=left>[0-9] people found/",$file,$match);
You need to delimit the search pattern using two of the same character, these must be alphanumeric or backslash, convention says use slashes 🙂
If you want you can capture just the bits needed using parentheses:
preg_match("/TD class=s align=left>([0-9]) people found/",$file,$match);
This will match one number between 0 and 9. Assuming that the number could be 10, or 100, you would need
preg_match("/TD class=s align=left>([0-9]+) people found/",$file,$match);
Where + is the regexp operator denoting 'one or more'