Well, for backup purposes, you probably want to copy, not move. Helps to quote around your variables too, things like "var" could confuse it without. Also, brackets shouldn't be around the variables in shell. Try this:
#!/bin/sh
FILE="/home/un/public_html/ctr/var/access.php"
BACKUP_FILE="/home/un/public_html/ctr/var/access2.php"
mv $FILE $BACKUP_FILE
Then give it permissions(chmod 755), and run it. /path/to/backup_script.sh