im assuming you have one header file that you include in all scripts
in this file, where you include your css file, add this code:
if (!isset($toggleCSS) || $toggleCSS != "false")
{
echo "<LINK REL=StyleSheet HREF='style.css' TYPE='text/css'>\n";
}
when you want to toggle CSS as being 'off' or not present, your link would look like this:
<a href='<? echo $PHP_SELF; ?>?toggleCSS=false'>Click here to disable CSS</a>