let's say you are looking for a field called "email"
$fields = mysql_list_fields('database_name', 'table_name');
$columns = mysql_num_fields($fields);
for ($i = 0; $i < $columns; $i++) {$field_array[] = mysql_field_name($fields, $i);}
if (!in_array('email', $field_array))
{
$result = mysql_query('ALTER TABLE table_name ADD email VARCHAR(10)');
}