Try collecting your data - all the info entered in the form are contained within the $_POST global. (If you're having nothing returned, try $HTTP_POST_VARS). Make sure, tho', that you're telling the from the right action. Usually, I do it up with the html form in the contact.htm page, the form action set to something like "thanks.php", which contains a little "thank you for your interest blah blah" and has the code listed below. Also make sure to set your form method to post. And, because I'm beating a dead horse here, make sure you've named all of your form fields what they're called in the php code (make sure the e-mail field is called "email", name is called "name", etc... Simple, but it's bitten me in the butt more times than I can count...)
Mail code in "thanks.php"...
<?php
$to="email@address.com";
$from = $_POST['email'];
$body=$_POST['name']."\n\r".$_POST['email']."\n\r".$_POST['qualifications'];
$subject="Staff Application";
mail($to, $subject, $body, "From:$from");
?>
This will deliver an e-mail to the addy in the $to variable that places carriage returns between each of the e-mail's main three pieces of body data.
HTH!