Well, as a piece of SQL it means what it says: You have tried to insert a record into a table that has at least 1 unique index, and the record you are trying to insert would duplicate a value already taken in that index. If there is no record with the value actually in the table then your index is screwed and needs rebuilding. I can see two '1's in your query so it could be either field. Look for the index.
If you want to overwrite the original record then use REPLACE instead of INSERT, the syntax is identical although replace does have some parameters for itself.