Update:
Well I got it sorted out. Thanks! Apparently I just had to mess with my PHP.ini and extension file setup. As you probably know, there are multiple ways to run PHP and Apache together. Either by placing some of the PHP files directly into the Apache folder or creating references to them and etc...
All I did was move the DLLs to System32 rather than relying on php.ini to find them (in the same folder) and it worked.
But now there's another problem. When I run phpMyAdmin I get this error from phpMyAdmin:
#2003 - The server is not responding
Anyone know why? Thanks.