Why not look at http://dev.mysql.com/doc/mysql/en/date-and-time-functions.html and find something like this:
SELECT
pc_number, SEC_TO_TIME(SUM(TIME_TO_SEC(pc_duration))) duration
FROM phonecalls
GROUP BY pc_number
?
CREATE TABLE phonecalls (
pc_id int(10) NOT NULL auto_increment,
pc_number int(5) NOT NULL default '0',
pc_started datetime NOT NULL default '0000-00-00 00:00:00',
pc_duration time NOT NULL default '00:00:00',
PRIMARY KEY (pc_id)
) TYPE=MyISAM;
INSERT INTO phonecalls VALUES
(1, 12345, '2005-03-29 11:45:56', '00:01:00'),
(2, 12345, '2005-03-29 11:46:14', '00:01:45'),
(3, 44444, '2005-03-29 11:46:31', '00:02:00'),
(4, 12345, '2005-03-29 11:46:47', '00:01:25'),
(5, 44444, '2005-03-29 11:47:03', '00:58:00');
should return 00:04:10 for 12345 and 01:00:00 for 44444