No - that value is only available through $REQUEST and $GET, if you're dragging their user level from a database and essentially caching in it $_SESSION['level'] then the only thing that can change that is your script setting the value explicitly.
Even if you've got register globals on (not the best idea) and in the script you have a variable called $userLevel and in the script say
$userLevel = $_SESSION['leve'];
If they've put in the url the variable with that name it will be overwritten by your script version.