I think the latest version only compiles against 7.4/8.0, or maybe even just 8.0.
It's very cool to write a trigger or function in PHP, then write an app in php that calls postgres, which calls php, which...
well anyway, you get the picture.
And then there's pltcl, plR, plruby, plpgsql, plsh, plJ, and a few others I can't remember right now.
It's funny that postgresql has more languages capable of being used inside it than .net probably does. hehe