Connery defined the role. The other guys have just had trouble redefining it, as they weren't (and can't be, by definition/logic/reality) Connery.
Moore ... pretty good, but I didn't like his brogue so well.
Lazenby ... never had a chance, did he?
Dalton ... well, not bad, for what he did. But what he tried to do may not have been so good. A kinder, gentler Bond. Sensitive, even. As Buzz notes, it kind of goes against the grain. I enjoy the films --- they were written pretty well, I think, (e.g., you had to love "Kara Milovy"), but it's certainly not like the old stuff...
Brosnan ... wish I looked half as good. As for the stuff, it's going the way of all movies ... computers/SFX trying to make up for a lack of detail/talent/enthusiasm in scriptwriting, continuity, directorial ability, passion in actors .... The last one, I wished I'd brought my earplugs . . . the "disavowed agent" thing was good, as was the slashing up of the London club, but overall there was so much "adrenaline pumping action" that you really came up numb, if you ask me.
He does have at least the concept of the debonnaire/cavalier bravado, though . . . I might put Pierce at #2, ahead of Moore, but I'm not sure . . . .