The people who use arrays a lot, and understand them, think you cannot get by without them. I disagree. I never use them from choice, and so rarely have to use them at all. I know how to get data out of the post array etc, and how to address the data in a query resultset.
Beyond that, I've not found anything that I can't do without them; though of course I'm sure they would make a few things more efficient, if less transparent. Code/logic transparency is paramount for me while processing power is so cheap now that saving a few processor cycles is unneccessary.
If you are using mysql then concentrate on learning sql thoroughly, it will pay you greater dividends now and in the future.
So long as you understand what an array is, leave arrays untill you have to learn about a specific function for a specific purpose.