To perform multiple queries with the same query, you must put a ; at the end of every line before the first one. And, combining strings is not done with the +, but the .
//see if there are any images awaiting validation
$searchvalidate1 = mysql_query("SELECT * from pictures where image1 != '' AND image1ver = '0';") or die(mysql_error());
$numval1 = mysql_num_rows($searchvalidate1);
$searchvalidate2 = mysql_query("SELECT * from pictures where image2 != '' AND image2ver = '0';") or die(mysql_error());
$numval2 = mysql_num_rows($searchvalidate2);
$searchvalidate3 = mysql_query("SELECT * from pictures where image3 != '' AND image3ver = '0';") or die(mysql_error());
$numval3 = mysql_num_rows($searchvalidate3);
$searchvalidate4 = mysql_query("SELECT * from pictures where image4 != '' AND image4ver = '0';") or die(mysql_error());
$numval4 = mysql_num_rows($searchvalidate4);
$searchvalidate5 = mysql_query("SELECT * from pictures where image5 != '' AND image5ver = '0';") or die(mysql_error());
$numval5 = mysql_num_rows($searchvalidate5);
$searchvalidate6 = mysql_query("SELECT * from pictures where image6 != '' AND image6ver = '0'") or die(mysql_error());
$numval6 = mysql_num_rows($searchvalidate6);
$numval = $numval1.$numval2.$numval3.$numval4.$numval5.$numval6;
In addition to this, you must use mysqli_multi_query to run the query, instead of a normal mysqli_query.