Your query would produce the titles in ascending order from the oldes (or first to last) as just the title. I am assuming the ques_id is an int data type of some sort that is auto incrementing and if you altered the query just a little you would see something like the below.
id_que title_que
1 Where is the beef?
2 Florida Vacation
3 War in Iraq,
4 Pot Roast Recipe
5 Using Chemicals Safely
SELECT id_ques, title_ques
FROM ques
ORDER BY id_ques ASC
LIMIT 0 , 5
Would produce the above and conversly if you used DESC instead of ACS it would show the fake titles above in order of the newest to the oldest. I mean you only have two columns and there really are only so many ways to order them so what is it that you really want them to do?