On your index.php page you should have a list of product generated from your database with thumbnail pictures with links like
<a href=javascript:popUp('show.php?product=1')><img src=images/products/imagethumb.jpg"></a>
Now when a user clicks the link it will load show.php with the product id being passed in the querystring.
<?php
//show.php
//connect to your database
mysql_connect('localhost', 'your_db_username', 'your_db_password');
mysql_select_db("your_db_name");
$id = $_GET['product']; //get the product id using GET
//SQL to get imagefull name from db
$sql = "SELECT imagefull FROM koruproduct WHERE id = '$id' LIMIT 1;";
$result = mysql_query($sql);
$row = mysql_fetch_assoc($result);
$imagefull = $row["imagefull"];
//echo html
echo '<div class="productlarge">';
echo '<div><img src="images/products/'.$imagefull.'.jpg"></div>';
echo '</div>';
?>