Worked!
The explode function really helped out. Of course, for what I was doing I was required to create a few more variables to make this work for what I needed.
Here's the code I performed for testing it.
<?
$server="SQLSERVER";
$username="user";
$password="password";
$sqlconnect=mssql_connect($server, $username, $password);
$sqldb=mssql_select_db("DATABASE",$sqlconnect);
$sqlquery="SELECT * FROM Manager;";
$results= mssql_query($sqlquery);
while ($row=mssql_fetch_array($results)){
$ManagerEmail = $row['ManagerEmail'];
$ManagerName = $row['ManagerName'];
$option_block .= '<option value="' . $ManagerEmail . '|' . $ManagerName . '">' . $ManagerName . '</option>';
} ?>
<? mssql_close($sqlconnect); ?>
<form id="form1" name="form1" method="post" action="sqlserver.php">
<select name="NeededInfo">
<? echo $option_block; ?>
</select>
<label>
<input type="submit" name="Submit" value="Submit" />
</label>
</form>
<br />
<br />
<? // Explode
$separated = explode("|", $NeededInfo);
$email = $separated[0]; // email address
$Supervisor = $separated[1]; // name
?>
<? echo $email; ?> <br /><br />
<? echo $Supervisor; ?>