If its in the database already you can just write a query similar to this,
select * from stations;
If you have columns lets say, name and link, then you can just output them,
while ($row = mysql_fetch_array($query, MYSQL_ASSOC) {
// $row['name']; will be the name for the current station name
// $row['link']; will be the link to the current station
}
And in each iteration you can have it output a row in a table,
echo "
<tr>
<td>$row[name]</td><td><a href=\"$row[link]\">Listen Now</a></td>
</tr>";
But you will need to connect to the database before you can query it, if you don't know how heres how.
//$db is your database connection reference link
$db = mysql_connect('host', 'username', 'password');
mysql_select_db('database');