Well, for one, this function returns an array, so there's no need to use [man]array/man to encase the returned value inside an array.
As for using an associative array, it's really simple:
echo $array['key_here'];
echo's the value for the index (or key) "key_here" from the array $array. So, for your $array_exif (once you remove the extra array() stuff), you'd echo whichever keys you want... DateTimeOriginal for example.
For more information on arrays, see this man page: [man]language.types.array[/man].