As NogDog said, the difference is going to be negligible - so much to the point that I'm willing to bet that you can't accurately measure it from within the script (as has been suggested).
Regardless of whether you have the HTML in an echo() statement or whether you have it outside the PHP tags, PHP still has to process the entire file and look for PHP code, so it's going to go over the HTML one way or the other. I doubt a call to echo() is going to be noticeably slower than simply moving the HTML outside of the PHP tags.
In the end, it's pretty much up to you - which version would you rather code?