If you read Wikipedia, there are plenty of CAPTCHA crackers out there. Some of the viable alternatives are to ask them to finish a famous saying like:
"One fish, Two Fish, Red Fish, _________" (Blue Fish)
Or ask them for some simple math:
"What is the square root of one hundred?" (10)
Problem with those solutions are that you usually have to have a "database" of sayings that you can randomly draw upon to use. So having like 5 or 6 sayings is no good, having 5 or 6 hundred is better 😉
But since some CAPTCHAs are being cracked via OCR software, you're better off using some "misspellings" sometimes to help counteract OCR software. Something like:
"What is three plus fuor?"
While that may be a fine for a while, it really won't stop them. One of the better systems I've seen is reCAPTCHA which uses millions of lines of text from books to make a fuzzy image of two words. For examples, just go to their homepage.
Just some more information for you to go on 😉