Oops, my real life code is a bit more complicated and I always get lost in arrays...
Here's how my array against ($usedValues) which I need to compare against look:
print_R($usedValues);
//WILL RETURN
//Array ( [0] => Array ( [name] => a [size] => 20136) [1] => Array ( [name] => c [size] => 15447) [2] => Array ( [name] => e [size] => 15447))
Clearly
$arrayDiff = array_diff($allValues, $usedValues);
won't work... Tried but without success
$arrayDiff = array_diff($allValues, $usedValues[$key]['name']);