If you're on a local network, you should be able to use the network address as well. Check the "Listen" value in httpd.conf.
If you want to use a named server, find the file named "hosts" (probably /etc/hosts on linux, c:\windows\system32\drivers\etc\hosts on Windows) and edit it. For instance you can add a line like:
192.168.0.10 example.com
or
192.168.0.10 myserver
or
127.0.0.1 myserver
Google for "hosts file tutorial" to find out more.