Depends on what format your colour is in. But to convert between CMY and RGB colour models you subtract each the R, G, and B components from whatever values they'd have in white and that would give you the C, M, and Y components. Converting back of course is vice-versa.
That's the only difference. In RGB you start with black and add red, green and blue; in CMY you start with white and subtract red, green and blue (subtracting red is the same as adding cyan).
What any of that has to do with one mixing being "more true" than another or not of course depends on how you measure "trueness".