what you store in textfield, you will send that with POST, but a link is your submit "button"...
you can store fix values in hidden field as well, or store that in database or Session variables..
and store in URL site ID only, not personal data(username&password&email&mail-body)
so i don't know what's your aim with your question.
If its needed to store something in url,
use the <form method="POST" action="form_to.php?variable1=1&variable2=2">
....
and then you can use normal submit button