Well first the type of encryption would be a very important piece of information.
But before you go posting that, most encryptions were intended to not be broken. And for the ones that someone did figure out there are some great tricks for hiding the actual password even then.
For the most part if the password field in the database doesn't say "unclebob1" you have very little chance of finding out what it is.
You have to realize people use he same password for everything like there email or their online bank statements and in all reality it is best to keep that data away from our eyes. Even the most honest amongst us may get tempted otherwise.
May I ask why you would need to read there passwords? Maybe that answer will have a solution for you.