First of all, I've never used WAMP so I can't tell you exactly how it's supposed to work, but I do know how to setup PHP and Apache separately, which is why I say the following:
Never move any PHP-related files from outside the main PHP directory (e.g. c:/wamp/bin/php/) - especially not into a Windows system directory. Not only is it unnecessary, but it creates problems when you change versions around.
So the first thing you need to do is remove all copies of files you've placed outside of the main PHP directory.
Then, check to make sure that the main PHP directory where files such as libmysql.dll should be located (e.g. c:/wamp/bin/php/php5.2.9-2/ from the looks of it) is in your system's PATH environment variable.
Next, since you're talking about the MySQLi extension, did you also check the extension= line for this module? The one you showed us above points to the older MySQL extension, not mysqli.
Don't forget that after making changes to your php.ini file you must restart Apache for those changes to take effect.