No, you would create a database with at least 5 fields:
1.) ID (a unique ID for each row, typically done with auto_increment)
2.) show (the TV Show Title)
3.) day (the day this tv show will air)
4.) start (the time this show will start)
5.) end (the time this show will end)
Now, say show PFKU runs on two nights at the same time (Tues 7pm - 8 pm, Thur 7pm - 8pm) then you would have 2 rows in your shows table, one for Tues the other for Thurs. The start time would be 19:00 (7:00 pm) and the end time would be 20:00 (8:00 pm).
Then when retrieving the results from the database, you can order by start to get the listing of shows in the order they will actually be shown in.