Note that as a matter of simplification, you could replace this:
$selectNew = mysql_query("SELECT * FROM users WHERE username = '$username'");
$check = mysql_num_rows($selectNew);
if($check == "1") {
mysql_query("DELETE FROM users WHERE username = '$username'");
}
with this:
mysql_query("DELETE FROM users WHERE username = '$username'");
$check = mysql_affected_rows();
In other words, just perform the DELETE query and see if it did anything... no need to do a SELECT first.