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I'd say the first steps to do would be to plan and design the MySQL database. So, how much of that have you done?
For example, using nothing but the bits of information included in your post above, I would probably start with a schema like:
[b]Clients[/b]
id - UNSIGNED INT, AUTO_INCREMENT, PRIMARY KEY
(any other relevant attributes, e.g. names, addresses, whatever)
[b]Items[/b]
id - UNSIGNED INT, AUTO_INCREMENT, PRIMARY KEY
(any other relevant attributes, e.g. name, description, category, whatever)
[b]Quotes[/b]
id - UNSIGNED INT, AUTO_INCREMENT, PRIMARY KEY
client_id - FOREIGN KEY (Clients.id)
date - DATETIME
[b]Quote_Items[/b]
quote_id - FOREIGN KEY (Quotes.id)
item_id - FOREIGN KEY (Items.id)
quantity - UNSIGNED INT
price - DECIMAL
is_taxable - BOOL
Note you could consider adding things like 'subtotal' and 'total' as attributes to the 'Quotes' table; this would mitigate the work of calculating these values on-the-fly, but it also runs the risk of becoming out-of-sync if you do some modifications to the quote without updating these attributes.