Law enforcement eh? Before rediscovering my love of computing (cheese), I worked for the dept of Corrections in California for almost eight years
But that was then and this is now.
So you guys are thinking about NT? That's not my first choice. I didn't even know they made a Postgress variant for NT. One things is for sure. It will be easier to deal with the hardware (tape drive) from NT. However, you may wish to consider what you priorities are. A stable platform, or ease of use? Also, to help admin the Postgress db, there is a program called phpPgAdmin that enables db administration (for a good deal of things at least) through your browser. It can be found here.
http://www.phpwizard.net/projects/phpPgAdmin/
Hope that helps,
Terrence